The explanation behind this is : "There are various theories being debated as to the exact scientific explanation of the phenomenon, many scientists claim that it is a physical reaction and not a chemical one[4]. Water molecules strongly attract each other, linking together to form a tight connection around each bubble of carbon dioxide gas in the soda. To form a new bubble, water molecules must push away from one another. It takes extra energy to break this surface tension. So, in other words, water resists the expansion of bubbles in the soda.
When Mentos are dropped into soda, the gellan gum and gum arabic of the candy dissolves and breaks the surface tension. This disturbs the water connection, so that it takes less work to expand and form new bubbles. Each Mentos candy has thousands of tiny pores all over its surface. These tiny pores function as nucleation sites, perfect places for carbon dioxide bubbles to form. As soon as the Mentos enter the soda, bubbles form all over their surface. They quickly sink to the bottom, causing carbon dioxide to be released by the carbonated liquid with which they come into contact along the way. The sudden increase in pressure pushes all of the liquid up and out of the bottle."
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